{2-[2-(Isopropylamino)ethyliminomethyl]-5-methoxyphenolato}(thiocyanato-κN)nickel(II)
نویسندگان
چکیده
In the title mononuclear complex, [Ni(C(13)H(19)N(2)O(2))(NCS)], the Ni(II) ion is coordinated by one phenolate O atom, one imine N atom, and one amine N atom of a 2-[2-(isopropyl-amino)-ethyl-imino-meth-yl]-5-meth-oxy-phenolate Schiff base ligand, and by one N atom of a thio-cyanate ligand, forming a slightly distorted square-planar geometry.
منابع مشابه
Bis{2-[3-(dimethylammonio)propyliminomethyl-κN]-6-methoxyphenolato-κO 1}bis(thiocyanato-κN)nickel(II)
The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol-ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(4) geometries arising from two N,O-bidentate Schiff base ligands and two N-bonded thio-cyanate ions. The mol-ecular...
متن کامل{4-Bromo-2-[2-(isopropylamino)ethyliminomethyl]phenolato}thiocyanatocopper(II)
In the title mononuclear Schiff base copper(II) complex, [Cu(C(12)H(16)BrN(2)O)(NCS)], the Cu(II) ion is coordinated by two N atoms and one O atom from a Schiff base ligand, and by one N atom from a thio-cyanate anion, giving a square-planar geometry. There are long-range inter-actions between the Cu atom and S [3.151 (5) Å] and Br [3.929 (5) Å] atoms above and below the square plane.
متن کامل{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}(thiocyanato-κN)copper(II)
In the title mononuclear copper(II) complex, [Cu(C(12)H(17)N(2)O(2))(NCS)], the Cu(II) atom is four-coordinated by an NNO-donor set of the tridentate Schiff base ligand and the N atom of a terminal thio-cyanate ligand in a slightly distorted square-planar geometry.
متن کاملBis{2-[imino(phenyl)methyl]-5-methoxyphenolato-κ2 N,O 1}nickel(II)
The title complex, [Ni(C(14)H(12)NO(2))(2)], lies about an inversion center. The Ni(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and two N atoms from two 2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolate ligands. The dihedral angle between the symmetry-unique phenyl and benzene rings is 73.2 (1)°.
متن کامل{2-Bromo-4-chloro-6-[2-(diethylamino)ethyliminomethyl]phenolato-κ3 N,N′,O}(thiocyanato-κN)copper(II)
In the title compound, [Cu(C(13)H(17)BrClN(2)O)(NCS)], the Cu atom is in a slightly distorted square-planar geometry, coordinated by the three donor atoms of the ligand and the N atom of the isothio-cyanate group.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010